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Research on low nitrogen combustion mechanism and technology of gas boiler
- Categories:News
- Author:Shenzhen Zhongli Weiye Electromechanical Equipment Co., Ltd.
- Origin:Shenzhen Zhongli Weiye Electromechanical Equipment Co., Ltd.
- Time of issue:2021-06-09 14:11
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Research on low nitrogen combustion mechanism and technology of gas boiler
Basic Principles of Nitrogen Chemistry in Methane -Air Combustion Process
The combustion theory divides the generation of NOx into thermal NOx (Thermal NOx), fast NOx (Prompt NOx) and fuel NOx (Fuel NOx). The nitrogen content of natural gas is low, therefore, fuel-based NOx is not its main control type. Thermal NOx refers to the oxidation of N2 in the combustion air at high temperature to form NOx. Regarding the generation mechanism of thermal NOx, the Geridovich mechanism is generally used: when the temperature is lower than 1500 °C, the amount of thermal NOx generated is very small; when the temperature is higher than 1500 °C, the reaction rate will increase for every 100 °C increase in temperature. 6~7 times. In the actual combustion process, since the temperature distribution in the combustion chamber is not uniform, if there are local high temperature areas, more NOx will be generated in these areas, which may play a key role in the generation of NOx in the entire combustion chamber. Rapid NOx When the hydrocarbon fuel is burned and the fuel is rich, the reaction zone will generate NOx rapidly. In the actual combustion process, various factors change independently, and many parameters are constantly changing. Even the combustion of simple gas fuel must experience the mixing of fuel and air, and the combustion produces flue gas until it leaves the furnace. . The temperature of the furnace, the mixing degree of fuel and air, the residence time of flue gas in the furnace and other parameters that have a great impact on NOx emissions are constantly changing.
After the fuel and air mixture enters the furnace, the air temperature of the mixture rises rapidly due to the convection and radiation heating of the surrounding high temperature flue gas. When the ignition temperature is reached, the fuel begins to burn, at which point the temperature rises sharply to near adiabatic levels. At the same time, due to the convection and radiation heat exchange between the flue gas and the surrounding medium, the temperature gradually decreases until it is the same as the temperature of the surrounding medium, that is, the flue gas flows through the entire furnace while cooling. It can be seen that the flame temperature distribution in the furnace is actually non-uniform. Usually, the temperature at a certain distance from the burner outlet is high, and the temperature before and after it is lower, that is, there is a local high temperature area. Since the temperature in this zone is much higher than the average temperature level in the furnace, it has a strong influence on NOx generation: the higher the temperature, the more NOx is generated. Therefore, in the furnace, in order to suppress the generation of NOx, in addition to reducing the average temperature in the furnace, it is necessary to try to make the temperature distribution in the furnace uniform and avoid local high temperature.
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